Sustainable waste management solution turning waste plastics into valuable resources
Catalytic dewaxing targets the "undesirable" molecules in pyrolysis oil distillates, that is, those with poor cold flow properties (the wax oil).
Under the action of a specialized catalyst, the long-chain wax molecules are cracked into shorter-chain hydrocarbons, such as alkanes and alkenes.
This modifies the molecular structure and properties of the wax. This helps to get the best pyrolysis oil performance.
Plastic pyrolysis is the mechanism of thermally degrading long-chain plastic molecules into smaller molecules (oil, gas and char) using heat in an oxygen-free environment. Its process conditions and additional refining techniques determine the type of oil product obtained. Here's how three distinct oil products can be derived:
It is produced from standard pyrolysis under moderate temperatures without catalysts. The oil has high viscosity and remains solid at room temperature.
Plastics are composed of long-chain macromolecules (polymers) formed by the polymerization of numerous small molecules (monomers). Polyethylene (PE) is a macromolecule with a backbone made up of carbon atoms. These plastic polymers are stable, difficult to break down, and have strong covalent bonds.
Pyrolysis oil mainly consists of smaller hydrocarbon components, typically as alkanes, alkenes, and aromatics (C4–C20). These smaller molecules are more volatile and can be used as fuels or chemical feedstocks.
Using polyethylene (PE) as an example, its decomposition from macromolecules to micromolecules proceeds through the following stages:
1. C–C bond cleavage creates free radicals like (CH2–CH• or •CH2–CH2), which start the reaction.
2. These radicals undergo β-scission, producing smaller molecules (C2H4, CH4, C3H6) and more radicals.
3. Radical recombination terminates the reaction.
4. Through successive bond cleavages, the final pyrolysis oil mainly consists of different small molecules (C4H8, C6H6, etc.) formed.
Types of Plastic | Coming from |
---|---|
Low-Density Polyethylene | Cling films, fresh-meat protection bags, etc. |
High-Density Polyethylene | Plastic pallet, trash cans, etc. |
Polystyrene | Microwave lunch box, heat-resisting box, etc. |
Polypropylene | Fast food box, bowl of instant noodles box, etc. |
Other Plastics without chlorine and oxygen | Various sources |
Note: Polyolefin waste plastics like PP, PE, and PS accounted for 92% of total plastic products (28% PP, 46% LDPE and HDPE, and 18% PS). Because of their high proportion and chemical structure, these are the most commonly used feedstocks in pyrolysis.
Types of Plastic | Coming from |
---|---|
Polyethylene Terephthalate | Mineral water bottles, carbonated beverage bottles, etc. |
Polyvinyl Chloride | Raincoat, building materials, etc. |
Other plastics with chlorine and oxygen | Various sources |
Note: Plastics containing high amounts of oxygen (O₂) and chlorine (Cl) are not suitable for pyrolysis. These two substances pose risks to plastic pyrolysis machines, air quality, and worker safety.